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Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması

Yıl 2024, Cilt: 13 Sayı: 1, 223 - 235, 15.01.2024
https://doi.org/10.28948/ngumuh.1284143

Öz

Bu çalışmada, hacimsel olarak %15 oranında biyodizel içeren dizel-biyodizel yakıt karışımına (B15) alüminyum oksit (Al2O3) nanoparçacıkları ile bütil hidroksi tolüen (BHT), tersiyer bütil hidrokinon (TBHQ) ve karanfil esansiyel yağı (KEY) antioksidan katkı maddelerinin eklenmesinin yanma karakteristikleri, motor performansı ve egzoz emisyonlarına etkileri deneysel olarak incelenmiştir. Al2O3 nanoparçacıkları 100 ppm konsantrasyonunda ve antioksidan katkı maddelerinin her biri 2000 ppm konsantrasyonunda B15 yakıtına eklenmiştir. Elde edilen katkılı yakıtlar ile katkı içermeyen dizel ve B15 yakıtı dört zamanlı ve tek silindirli bir dizel motorda test edilmiştir. Al2O3 nanoparçacıklarının tek başına yakıt katkısı olarak kullanıldığında motor performansının iyileştiği, CO, HC ve is emisyonlarının azaldığı ancak aynı çalışma şartlarında NOX emisyonunun ortalama %30.36 oranında arttığı belirlenmiştir. Al2O3 nanoparçacıklarının ve antioksidan katkı maddelerinin birlikte kullanılması durumunda NOX emisyonu ortalama %7.63 oranında azalmış ve B15 yakıtına çok yakın motor performans değerleri elde edilmiştir. NOX emisyonunun azaltılmasında TBHQ antioksidan katkı maddesinin diğer antioksidanlara göre daha etkili olduğu belirlenmiştir.

Teşekkür

Biyodizel yakıtının temini için Kolza Biyodizel A.Ş.'ye ve yakıt numunelerinin analizi için sağladıkları teknik destekten dolayı OYAK Güzel Enerji Akaryakıt A.Ş. Samsun Yakıt Analiz Laboratuvarı çalışanlarına teşekkür ederiz.

Kaynakça

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Investigation of the effects of Al2O3 nanoparticles and various antioxidant additives on a diesel engine characteristic

Yıl 2024, Cilt: 13 Sayı: 1, 223 - 235, 15.01.2024
https://doi.org/10.28948/ngumuh.1284143

Öz

In this study, the effects of the addition of aluminium oxide (AI2O3) nanoparticles and butyl hydroxytoluene (BHT), tertiary butyl hydroquinone (TBHQ) and clove essential oil (CEO) antioxidant additives to a diesel-biodiesel fuel mixture (B15) containing 15% by volume biodiesel on combustion characteristics, engine performance and exhaust emissions were investigated experimentally. Al2O3 nanoparticles at the dosage of 100 ppm and each of the antioxidant additives at a concentration of 2000 ppm were added to the B15 fuel. The obtained test fuels with additives and the additive-free diesel and B15 fuel were tested in a four-stroke and single-cylinder diesel engine. It is determined that when Al2O3 nanoparticles are used alone as a fuel additive, engine performance improves, CO, HC and soot emissions decrease, but NOx emission increases by an average of 30.36% under the same operating conditions. It is found that when Al2O3 nanoparticles and antioxidant additives are added together to fuel, NOx emission decreases by 7.63% on average and engine performance values are very close to those of B15 fuel. It is concluded that the TBHQ antioxidant additive is more effective than other antioxidants in NOx emission reduction.

Kaynakça

  • N. Abas, A. Kalair and N. Khan, Review of fossil fuels and future energy technologies. Futures, 69, 31-49, 2015.https://doi.org/10.1016/j.futures.2015.03.003.
  • F. Yaşar, Comparision of fuel properties of biodiesel fuels produced from different oils to determine the most suitable feedstock type. Fuel, 264, 116817, 2020. https://doi.org/10.1016/j.fuel.2019.116817.
  • A. Demirbas, Biofuels sources, biofuel policy, biofuel economy and global biofuel projections. Energy conversion and management, 49, 2106-16, 2008. https://doi.org/10.1016/j.enconman.2008.02.020.
  • A. Çakmak, Improvement of exhaust emissions in a diesel engine with the addition of an oxygenated additive to diesel-biodiesel blends. Energetika, 68, 79–90, 2022. https://doi.org/10.6001/energetika.v68i1.4859.
  • R. Behçet, H. Oktay, A. Çakmak and H. Aydin, Comparison of exhaust emissions of biodiesel-diesel fuel blends produced from animal fats. Renewable and Sustainable Energy Reviews, 46, 157–65, 2015. https://doi.org/10.1016/j.rser.2015.02.015.
  • V. K. Mishra and R. Goswami, A review of production, properties and advantages of biodiesel. Biofuels, 9, 273–289, 2018. https://doi.org/10.1080/17597269.2017.1336350.
  • M. Gülüm, An investigation of effects of diesel fuel-vegetable oil-diethylene glycol dimethyl ether fuel blends on performance, combustion and emission characteristics of a diesel engine. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 12:1, 2023.
  • L. Leng, W. Li, H. Li, S. Jiang and W. Zhou, Cold Flow Properties of Biodiesel and the Improvement Methods: A Review. Energy & Fuels, 34, 10364–83, 2020. doi:10.1021/acs.energyfuels.0c01912.
  • A. Syafiuddin, J. H. Chong, A. Yuniarto and T. Hadibarata, The current scenario and challenges of biodiesel production in Asian countries: A review. Bioresource Technology Reports, 12, 100608, 2020. https://doi.org/10.1016/j.biteb.2020.100608.
  • C. V. Jemima Romola, M. Meganaharshini, S. P. Rigby, I. Ganesh Moorth, R. Shyam Kumar and S. Karthikumar, A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel. Renewable and Sustainable Energy Reviews, 145, 111109, 2021. https://doi.org/10.1016/j.rser.2021.111109.
  • M. A. Fazal, M. R. Jakeria, A. Haseeb and S. Rubaiee, Effect of antioxidants on the stability and corrosiveness of palm biodiesel upon exposure of different metals. Energy, 135, 220–226, 2017. https://doi.org/10.1016/j.energy.2017.06.128.
  • M. A. Fazal, A. Haseeb and H. H. Masjuki, Comparative corrosive characteristics of petroleum diesel and palm biodiesel for automotive materials. Fuel Processing Technology, 91, 1308–15, 2010. https://doi.org/10.1016/j.fuproc.2010.04.016.
  • R. K. Saluja, V. Kumar and R. Sham, Stability of biodiesel – A review. Renewable and Sustainable Energy Reviews, 62, 866–81, 2016. https://doi.org/10.1016/j.rser.2016.05.001.
  • M. Sui and F. Li, Effect of TEPA on oxidation stability and metal ion content of biodiesel. Renewable Energy, 143, 352–358, 2019. https://doi.org/10.1016/j.renene.2019.04.128.
  • G. Uğuz, A. Çakmak, C. da. Bento and N. Karakullukçu, Experimental investigation of fuel properties and engine operation with natural and synthetic antioxidants added to biodiesel. Biofuels, 14, 405–420, 2023. https://doi:10.1080/17597269.2022.2156049.
  • E. A. Decker, J. Alamed and I. A. Castro, Interaction between polar components and the degree of unsaturation of fatty acids on the oxidative stability of emulsions. Journal of the American Oil Chemists' Society, 87, 771–780, 2010. https://doi.org/10.1007/s11746-010-1556-3.
  • L. C. de Menezes, E. R. de Sousa, G. S. da Silva, A. L. B. Marques, H. D. C. Viegas and M. J. C. Dos Santos, Investigations on Storage and Oxidative Stability of Biodiesel from Different Feedstocks Using the Rancimat Method, Infrared Spectroscopy, and Chemometry. ACS Omega, 7, 30746–55 2022. https://doi.org/10.1021/acsomega.2c01348.
  • F. Zhang, J. Li, S. Yang and Y. Bi, Inhibitory effect of antioxidants on biodiesel crystallization: Revealing the role of antioxidants. Fuel, 297, 120782, 2021. https://doi.org/10.1016/j.fuel.2021.120782.
  • J. B. Heywood, Internal combustion engine fundamentals. McGraw-Hill, New York, 1988.
  • C. P. Fenimore, The ratio NO2 NO in fuel-lean flames. Combustion and Flame, 25, 85–90, 1975. https://doi.org/10.1016/0010-2180(75)90071-1.
  • E. Ileri and G. Koçar, Experimental investigation of the effect of antioxidant additives on NOx emissions of a diesel engine using biodiesel. Fuel, 125, 44–49, 2014. https://doi.org/10.1016/j.fuel.2014.02.007.
  • H. Hosseinzadeh-Bandbafha, D. Kumar, B. Singh, H. Shahbeig, S. S. Lam and M. Aghbashlo, Biodiesel antioxidants and their impact on the behavior of diesel engines: A comprehensive review. Fuel Processing Technology, 232, 107264, 2022. https://doi.org/10.1016/j.fuproc.2022.107264.
  • M. G. Bidir, N. K. Millerjothi, M. S. Adaramola and F. Y. Hagos, The role of nanoparticles on biofuel production and as an additive in ternary blend fuelled diesel engine: A review. Energy Reports, 7, 3614–27, 2021. https://doi.org/10.1016/j.egyr.2021.05.084.
  • I. Sezer, Effect of nano materials additives on fuel properties and combustion characteristics. Journal of the Faculty of Engineering and Architecture of Gazi University, 34, 115–35 2019. https://doi.org/10.17341/gazimmfd.416469.
  • A. Tuan Hoang, M. Xuan Le, S. Nižetić, Z. Huang, Ü. Ağbulut and I. Veza, Understanding behaviors of compression ignition engine running on metal nanoparticle additives-included fuels: A control comparison between biodiesel and diesel fuel. Fuel, 326, 124981, 2022;. doi:https://doi.org/10.1016/j.fuel.2022.124981.
  • A. Yakın, R. Behcet, H. Solmaz and S. Halis, Testing sodium borohydride as a fuel additive in internal combustion gasoline engine. Energy, 254, 124300. 2022. https://doi.org/10.1016/j.energy.2022.124300.
  • V. Dhana Raju, P. S. Kishore, K. Nanthagopal, and B.Ashok, An experimental study on the effect of nanoparticles with novel tamarind seed methyl ester for diesel engine applications. Energy conversion and management, 164, 655–66, 2018. https://doi.org/10.1016/j.enconman.2018.03.032.
  • A. Gaur, G. Dwivedi, P. Baredar and S. Jain, Influence of blending additives in biodiesel on physiochemical properties, engine performance, and emission characteristics. Fuel, 321, 124072 2022. https://doi.org/10.1016/j.fuel.2022.124072.
  • B. Ashok, K. Nanthagopal, R. Subbarao, A. Johny, A. Mohan and A. Tamilarasu, Experimental studies on the effect of metal oxide and antioxidant additives with Calophyllum Inophyllum Methyl ester in compression ignition engine. Journal of Cleaner Production, 166, 474–84, 2017. https://doi.org/10.1016/j.jclepro.2017.08.050.
  • B. Ashok, K. Nanthagopal, A. Mohan, A. Johny and A. Tamilarasu, Comparative analysis on the effect of zinc oxide and ethanox as additives with biodiesel in CI engine. Energy, 140, 352–64, 2017. https://doi.org/10.1016/J.ENERGY.2017.09.021.
  • S. Krishnakumar, T. M. Y. Khan, C. R. Rajashekhar, M. E.. Soudagar, A. Afzal and A. Elfasakhany, Influence of graphene nano particles and antioxidants with waste cooking oil biodiesel and diesel blends on engine performance and emissions. Energies, 14, 4306, 2021. https://doi.org/10.3390/en14144306.
  • A. Prabu, I. J. I. Premkumar and A. Pradeep, An investigation on the performance, combustion and emission characteristics of CI engine on the addition of antioxidants, oxygenates and nanoparticles as additives in Jatropha biodiesel. International Journal of Ambient Energy, 41, 121–128. 2020. https://doi.org/10.1080/01430750.2018.1443281.
  • S. N. K. Reddy and M. M Wani, An investigation on the performance and emission studies on diesel engine by addition of nanoparticles and antioxidants as additives in biodiesel blends. International Review of Applied Sciences and Engineering, 12, 111–118, 2021. https://doi.org/10.1556/1848.2020.00157.
  • E. B. Shevchenko, A. M. Danilov and V. N. Kameneva, Oxidation resistance of biodiesel. Russian Journal of Applied Chemistry, 90, 1015–1018 2017. https://doi.org/10.1134/S1070427217060246.
  • H. Tang, A. Wang, S. O. Salley and K. Y. S. Ng, The Effect of Natural and Synthetic Antioxidants on the Oxidative Stability of Biodiesel. Journal of the American Oil Chemists' Society, 85, 373–382 2008. https://doi.org/10.1007/s11746-008-1208-z.
  • H. A. Deveci, N. Gökhan, M. Ali Kırpık, A. Harmankay and Y. Yıldız, Fenolik bileşik içeren bitkisel antioksidanlar. Kafkas Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 9, 26–32, 2016.
  • K. R. Spacino, E. T. Da Silva, K. G. Angilelli, I. Moreira, O. F. Galão and D. Borsato, Relative protection factor optimisation of natural antioxidants in biodiesel B100. Industrial Crops and Products, 80, 109–14. , 2016. https://doi.org/10.1016/j.indcrop.2015.11.034.
  • M. Rocío Teruel, M. D. Garrido, M. C. Espinosa and M. B. Linares, Effect of different format-solvent rosemary extracts (Rosmarinus officinalis) on frozen chicken nuggets quality. Food chemistry, 172, 40–6, 2015. https://doi.org/10.1016/j.foodchem.2014.09.018.
  • C. H. Lau, S. Gan, H. L. N. Lau, L. Y. Lee, S. Thangalazhy-Gopakumar and H. K. Ng, Insights into the effectiveness of synthetic and natural additives in improving biodiesel oxidation stability. Sustain Energy Technology Assessments, 52, 102296. 2022. https://doi.org/10.1016/j.seta.2022.102296.
  • G. Uğuz, Antioxidant effect of clove oil on biodiesel produced from waste cooking oil. Biomass Conversion Biorefinery, 13(1), 367-373, 2023. https://doi.org/10.1007/s13399-021-01679-4.
  • G. Uguz, Inhibitory effect of thyme oil as an antioxidant for waste cooking oil biodiesel crystallization. Energy & Environment, 34(1), 176-192, 2023. https://doi.org/10.1177/0958305X211061346.
  • L. Silva de Sousa, C. Verônica Rodarte de Moura and E. Miranda de Moura, Action of natural antioxidants on the oxidative stability of soy biodiesel during storage. Fuel, 288, 119632, 2021. https://doi.org/10.1016/j.fuel.2020.119632.
  • N. Jeyakumar, Z. Huang, D. Balasubramanian, A. T. Le, X. P. Nguyen and P. L. Pandian, Experimental evaluation over the effects of natural antioxidants on oxidation stability of binary biodiesel blend. International Journal of Energy Research, 46, 20437–61, 2022. https://doi.org/10.1002/er.7956.
  • G. Karunanithi and A. M. S. Varadappan, Exploring the effectiveness of novel Coffea Arabica leaf pigment as a natural antioxidant additive for date seed biodiesel. Fuel, 324, 124561, 2022. https://doi.org/10.1016/j.fuel.2022.124561.
  • K. K. Pandey and S. Murugan, Effect of Pongamia pinnata leaves extracted natural antioxidant doped in biodiesel--diesel blend run low heat rejection engine. International Journal of Environmental Science and Technology, 20, 13159–13178, 2023. https://doi.org/10.1007/s13762-023-04777-0.
  • S. N. K. Reddy and M. M. Wani, A comprehensive review on effects of nanoparticles-antioxidant additives-biodiesel blends on performance and emissions of diesel engine. Applied Science and Engineering Progress, 13(4), 285–298, 2020.
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  • B. S. Chauhan, N. Kumar and H. M. Cho, A study on the performance and emission of a diesel engine fueled with Jatropha biodiesel oil and its blends. Energy, 37, 616–622 2012. https://doi.org/10.1016/j.energy.2011.10.043.
  • E. Rajasekar and S. Selvi, Review of combustion characteristics of CI engines fueled with biodiesel. Renewable and Sustainable Energy Reviews, 35, 390–399, 2014. https://doi.org/10.1016/j.rser.2014.04.006.
  • S. M. Mousavi, R. K. Saray, K. Bahlouli, K. Poorghasemi, A. Maghbouli and A. Sadeghlu, Effects of pilot diesel injection strategies on combustion and emission characteristics of dual-fuel engines at part load conditions. Fuel, 258, 116153. 2019. https://doi.org/10.1016/j.fuel.2019.116153.
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Toplam 63 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Makine Mühendisliği
Bölüm Araştırma Makaleleri
Yazarlar

Abdülvahap Çakmak 0000-0003-1434-6697

Erken Görünüm Tarihi 11 Aralık 2023
Yayımlanma Tarihi 15 Ocak 2024
Gönderilme Tarihi 16 Nisan 2023
Kabul Tarihi 24 Kasım 2023
Yayımlandığı Sayı Yıl 2024 Cilt: 13 Sayı: 1

Kaynak Göster

APA Çakmak, A. (2024). Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, 13(1), 223-235. https://doi.org/10.28948/ngumuh.1284143
AMA Çakmak A. Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. NÖHÜ Müh. Bilim. Derg. Ocak 2024;13(1):223-235. doi:10.28948/ngumuh.1284143
Chicago Çakmak, Abdülvahap. “Al2O3 nanoparçacıklarının Ve çeşitli Antioksidan Katkı Maddelerinin Dizel Motor Karakteristiklerine Etkilerinin araştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13, sy. 1 (Ocak 2024): 223-35. https://doi.org/10.28948/ngumuh.1284143.
EndNote Çakmak A (01 Ocak 2024) Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13 1 223–235.
IEEE A. Çakmak, “Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması”, NÖHÜ Müh. Bilim. Derg., c. 13, sy. 1, ss. 223–235, 2024, doi: 10.28948/ngumuh.1284143.
ISNAD Çakmak, Abdülvahap. “Al2O3 nanoparçacıklarının Ve çeşitli Antioksidan Katkı Maddelerinin Dizel Motor Karakteristiklerine Etkilerinin araştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi 13/1 (Ocak 2024), 223-235. https://doi.org/10.28948/ngumuh.1284143.
JAMA Çakmak A. Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. NÖHÜ Müh. Bilim. Derg. 2024;13:223–235.
MLA Çakmak, Abdülvahap. “Al2O3 nanoparçacıklarının Ve çeşitli Antioksidan Katkı Maddelerinin Dizel Motor Karakteristiklerine Etkilerinin araştırılması”. Niğde Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, c. 13, sy. 1, 2024, ss. 223-35, doi:10.28948/ngumuh.1284143.
Vancouver Çakmak A. Al2O3 nanoparçacıklarının ve çeşitli antioksidan katkı maddelerinin dizel motor karakteristiklerine etkilerinin araştırılması. NÖHÜ Müh. Bilim. Derg. 2024;13(1):223-35.

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